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Beilstein J. Org. Chem. 2014, 10, 1808–1816, doi:10.3762/bjoc.10.190
Graphical Abstract
Figure 1: Structure of sacrolide A (1).
Figure 2: Selected COSY (bold lines) and HMBC (arrows) correlations for sacrolide A (1).
Scheme 1: Initial derivatization strategy for the stereochemical analysis of sacrolide A (1).
Scheme 2: Determination of the stereochemistry of sacrolide A (1).
Scheme 3: Plausible biosynthesis of sacrolide A (1).
Figure 3: The effect of sacrolide A (1) on 3Y1 rat fibroblastic cells. (a) Control. (b) 45 min after exposure...
Figure 4: Extracted ion chromatograms for sacrolide A (1) molecular ion at m/z 307 [M – H]− in the LC–MS anal...